'The Vampire Diaries' Star Ian Somerhalder And Nina Dobrev
Nina Dobrev and Ian Somerhalder accept the award for favorite on-screen chemistry for their show "The Vampire Diaries" at the 2014 People's Choice Awards in Los Angeles, California January 8, 2014. REUTERS/Mario Anzuoni

"The Vampire Diaries" stars Ian Somerhalder and Nina Dobrev made one of the hottest couples of Hollywood both on and off-screen. Their recent breakup came as a jolt to their fans who continued to love them even after their split. Thus, making them win the prestigious "Favorite Onscreen Chemistry" honor at the 40Th Annual People's Choice Awards (2014). Along with the award, came a surprising giant kiss that Ian Somerhalder planted on Nina Dobrev's cheek and who then joked about their breakup. Continue to read, to find out what happened when the former couple came together on stage.

Ian Somerhalder and Nina Dobrev Back Together- 'The Vampire Diaries' Couple At People's Choice Awards 2014

On Wed. Jan 8, 2014, at 40th Annual People's Choice Awards 2014, the former couple won Favorite Onscreen Chemistry honor for their "The Vampire Diaries" roles of Elena Gilbert and Damon Salvatore. Even though the couple ended their relationship earlier in the year 2013, they continued to sizzle onscreen. Their unmatchable chemistry and love of their fans got them an award for best onscreen romance. While receiving the award, the two stars did not only come together amicably onstage, but they also joked about their breakup and ended it with a giant kiss.

"We started dating in real life," said "The Vampire Diaries'" Ian Somerhalder while accepting the award at 40th Annual People's Choice Awards (2014).

"And then we broke up in real life," added Nina Dobrev to Ian Somehalder's statement.

"And yet our characters are still dating on the show," continued Ian Somerhalder.

"It's a good thing it's not awkward!" joked Nina Dobrev onstage while pretending to be awkward with her ex-boyfriend Ian Somerhalder.

"Well, it's a good thing we have chemistry!" said Nina Dobrev at the end and Ian Somerhalder planted a giant kiss on his ex-girlfriend's cheek.

In the end, Ian Somerhalder thanked audience, before exiting the stage.

The "TVD" couple beat Derek & Meredith of "Grey's Anatomy, Kurt & Blaine from "Glee," Castle & Beckett from "Castle" and Emma & Hook From "Once Upon A Time" to win this award.

Nina Dobrev and Ian Somerhalder Back Together-'TVD' Actress Celebrated Her Birthday With Her Ex

The way "The Vampire Diaries" stars Ian Somerhalder and Nina Dobrev joked together on the stage of 40Th Annual People's Choice Awards, it showed that they still share a warm relationship.

The former couple got together, yet again in the moment of celebration. Nina Dobrev turned 25 on Jan. 9, 2014 and to the delight of their fans the duo came together.

Nina Dobrev celebrated her 25th birthday with her ex Ian Somerhalder and her best friend Julianne Hough. Julianne Hough also happens to be the sister of her other ex boyfriend.

Besides, making Nina's day special with a cake, Julianne Hough and Ian Somerhalder showered lots of love and good wishes for her via Twitter.

Julianne Hough wrote on Twitter: "Happy Birthday my beautiful @ninadobrev you are kind, smart, adventurous, loving, honest, beautiful,..."

She also shared a birthday photo on her Instagram account. Take a look HERE.

Ian Somerhalder wrote on Twitter: "Happy Birthday @ninadobrev !!! The world loves you!We all do;) Enjoy the moment, enjoy the day,enjoy the year!"

Kevin Williamson, the co-creator of "The Vampire Diaries" also shared a photo of the three stars Ian Somerhalder, Nina Dobrev and Julianne Hough together. In the photo, the trio looked happy together while holding the birthday cake. Click HERE to see the photo.

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