Actor Ian Somerhalder arrives at the 2014 People's Choice Awards
Actor Ian Somerhalder arrives at the 2014 People's Choice Awards in Los Angeles, California January 8, 2014. Reuters/Kevork Djsnsezian

The premiere episode of "The Vampire Diaries" Season 6 is still days away from airing but the CW Network has already released the details for the second episode of the brand new season. Aside from the synopsis for "The Vampire Diaries" Season 6, episode 2 titled "Yellow Ledbetter," the promo stills shared also teased what happened during Enzo (Michael Malarkey) and Stefan's (Paul Wesley) meeting.

The CW Network's official synopsis for "The Vampire Diaries" Season 6, episode 2 titled "Yellow Ledbetter" revealed that Enzo and Caroline (Candice Accola) will go on a road trip together once again but they will not be looking for Stefan's doppelganger this time.

The duo will actually encounter Stefan during their search for a way to bring back Damon (Ian Somerhalder) and Bonnie (Kat Graham). During their mission, Caroline will be shocked to find out what Stefan has been really doing since he left Mystic Falls.

A sneak peek photo from "The Vampire Diaries" Season 6, episode 2 showed another unpleasant moment between Enzo and Stefan when they finally saw each other. Fans can recall that the two clashed in "The Vampire Diaries" Season 5, episode 19 titled "Man on Fire" when Enzo was finding out the truth about his lady love, Maggie James (Heather Hemmens).

In CW Network's shared image, Enzo stabbed Stefan on the right hand which is most likely the Augustine vampire's way of tormenting the younger Salvatore vampire for basically abandoning his friends and not looking for a way to bring his brother back. Click HERE to see photo.

The episode synopsis in a Wet Paint report further revealed what the other TVD characters will be up to in "Yellow Ledbetter." Elena (Nina Dobrev) will be asking for Alaric's (Matt Davis) help so she could move on with her life after losing her boyfriend, Damon.

As for another grieving TVD character, Jeremy (Steven R. McQueen), Matt (Zach Roerig) becomes worried with his friend's new companion because she is a mysterious girl named Sarah (Gabrielle Walsh) who just arrived to Mystic Falls. Matt will also discover something about Tripp's (Colin Ferguson) connection to Mystic Falls.

Meanwhile, Damon and Bonnie are working together in solving the mystery of where they went when the Other Side finally crumbled and how they can go back home. However, the two never really got along so expected them to unenthusiastically work with each other or bicker around.

"The Vampire Diaries" Season 6 premiere episode titled "I'll Remember" is scheduled to air on Thursday night, Oct. 2, at 8 p.m. ET on the CW Network.

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